Limits...
catena-Poly[[diazido-manganese(II)]bis-[μ-1-(4-pyridylmeth-yl)-1H-benzimidazole]].

Liu CS, Wang JJ, Yan LF - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (-)).The L ligands and N(3) (-) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction.Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C-H⋯N hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (-)). Each of the Mn(II) ions lies on an inversion centre. The L ligands and N(3) (-) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C-H⋯N hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus

Part of the crystal packing showing the two-dimensional network in the title compound formed by interchain C—H···N hydrogen-bonded interactions (fine dashed lines). For the sake of clarity, only H atoms involved in the interactions are shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
getmorefigures.php?uid=PMC2914919&req=5

Fap3: Part of the crystal packing showing the two-dimensional network in the title compound formed by interchain C—H···N hydrogen-bonded interactions (fine dashed lines). For the sake of clarity, only H atoms involved in the interactions are shown.


catena-Poly[[diazido-manganese(II)]bis-[μ-1-(4-pyridylmeth-yl)-1H-benzimidazole]].

Liu CS, Wang JJ, Yan LF - Acta Crystallogr Sect E Struct Rep Online (2007)

Part of the crystal packing showing the two-dimensional network in the title compound formed by interchain C—H···N hydrogen-bonded interactions (fine dashed lines). For the sake of clarity, only H atoms involved in the interactions are shown.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914919&req=5

Fap3: Part of the crystal packing showing the two-dimensional network in the title compound formed by interchain C—H···N hydrogen-bonded interactions (fine dashed lines). For the sake of clarity, only H atoms involved in the interactions are shown.
Bottom Line: In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (-)).The L ligands and N(3) (-) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction.Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C-H⋯N hydrogen bonds.

View Article: PubMed Central - HTML - PubMed

ABSTRACT
In the title polymeric compound, [Mn(N(3))(2)(C(13)H(11)N(3))(2)](n), each Mn(II) centre is six-coordinated in an octahedral geometry by six N atoms from four 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two azide anions (N(3) (-)). Each of the Mn(II) ions lies on an inversion centre. The L ligands and N(3) (-) anions bridge adjacent Mn(II) centres, generating a polymeric chain running along the [110] direction. Adjacent polymeric chains are arranged in a two-dimensional network parallel to the (001) plane, linked by C-H⋯N hydrogen bonds.

No MeSH data available.


Related in: MedlinePlus