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(Isopropyl xanthato-κS,S')bis-(1,10-phenanthroline-κN,N')sodium(I).

Li F - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands.The Na atom is six-coordinate in a distorted trigonal anti-prism.A number of π-π stacking inter-actions involving the phen rings help to consolidate the crystal packing (centroid-centroid distances lie in the range 3.338-3.443 Å).

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Affiliation: Department of Chemistry, Luliang Higher College, Shanxi 033000, People's Republic of China.

ABSTRACT
The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal anti-prism. A number of π-π stacking inter-actions involving the phen rings help to consolidate the crystal packing (centroid-centroid distances lie in the range 3.338-3.443 Å).

No MeSH data available.


Crystal packing of (I) showing π-π stacking interactions (dashed lines) along the a axis.
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Fap2: Crystal packing of (I) showing π-π stacking interactions (dashed lines) along the a axis.


(Isopropyl xanthato-κS,S')bis-(1,10-phenanthroline-κN,N')sodium(I).

Li F - Acta Crystallogr Sect E Struct Rep Online (2007)

Crystal packing of (I) showing π-π stacking interactions (dashed lines) along the a axis.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914917&req=5

Fap2: Crystal packing of (I) showing π-π stacking interactions (dashed lines) along the a axis.
Bottom Line: The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands.The Na atom is six-coordinate in a distorted trigonal anti-prism.A number of π-π stacking inter-actions involving the phen rings help to consolidate the crystal packing (centroid-centroid distances lie in the range 3.338-3.443 Å).

View Article: PubMed Central - HTML - PubMed

Affiliation: Department of Chemistry, Luliang Higher College, Shanxi 033000, People's Republic of China.

ABSTRACT
The title compound, [Na(C(4)H(7)OS(2))(C(12)H(8)N(2))(2)], is monomeric, with the Na atom chelated by the S atoms of an i-propylxanthate ligand and the N atoms of two 1,10-phenanthroline (phen) ligands. The Na atom is six-coordinate in a distorted trigonal anti-prism. A number of π-π stacking inter-actions involving the phen rings help to consolidate the crystal packing (centroid-centroid distances lie in the range 3.338-3.443 Å).

No MeSH data available.