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(Di-2-pyridyl sulfide-κN,N')diiodidozinc(II).

Wriedt M, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: The Zn, S and I atoms are located on a crystallographic mirror plane.As usual for this type of complex, the sulfide group does not participate in zinc coordination.The dihedral angle between the two pyridine rings is 60.1 (1)°.

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Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Olshausenstrasse 40, D-24098 Kiel, Germany.

ABSTRACT
The title compound, [ZnI(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring adopting a boat conformation in which the Zn atom is coordinated by two iodide ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand within a slightly distorted tetra-hedron. The Zn, S and I atoms are located on a crystallographic mirror plane. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the two pyridine rings is 60.1 (1)°.

No MeSH data available.


Crystal structure of compound I with labelling and displacement ellipsoids drawn at the 50% probability level. Symmetry code: i = x, -y + 1/2, z.
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Fap1: Crystal structure of compound I with labelling and displacement ellipsoids drawn at the 50% probability level. Symmetry code: i = x, -y + 1/2, z.


(Di-2-pyridyl sulfide-κN,N')diiodidozinc(II).

Wriedt M, Jess I, Näther C - Acta Crystallogr Sect E Struct Rep Online (2007)

Crystal structure of compound I with labelling and displacement ellipsoids drawn at the 50% probability level. Symmetry code: i = x, -y + 1/2, z.
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914904&req=5

Fap1: Crystal structure of compound I with labelling and displacement ellipsoids drawn at the 50% probability level. Symmetry code: i = x, -y + 1/2, z.
Bottom Line: The Zn, S and I atoms are located on a crystallographic mirror plane.As usual for this type of complex, the sulfide group does not participate in zinc coordination.The dihedral angle between the two pyridine rings is 60.1 (1)°.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institut für Anorganische Chemie, Christian-Albrechts-Universität Kiel, Olshausenstrasse 40, D-24098 Kiel, Germany.

ABSTRACT
The title compound, [ZnI(2)(C(10)H(8)N(2)S)], contains a six-membered chelate ring adopting a boat conformation in which the Zn atom is coordinated by two iodide ions and by the two pyridyl N atoms of a single di-2-pyridyl sulfide ligand within a slightly distorted tetra-hedron. The Zn, S and I atoms are located on a crystallographic mirror plane. As usual for this type of complex, the sulfide group does not participate in zinc coordination. The dihedral angle between the two pyridine rings is 60.1 (1)°.

No MeSH data available.