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NaFe(TeO(3))(2).

Weil M, Stöger B - Acta Crystallogr Sect E Struct Rep Online (2007)

Bottom Line: The hydro-thermally prepared title compound, sodium iron(III) bis-[trioxotellurate(IV)], is isotypic with its Ga(III) analogue and consists of corrugated layers with an overall composition of [FeTe(2)O(6)](-) together with Na(+) cations.The layers extend parallel to (001) and are made up of [Fe(2)O(10)] edge-shared octa-hedral dimers and TeO(3) trigonal pyramids sharing vertices.The Na(+) cations are located in the cavities of this arrangement and link adjacent [FeTe(2)O(6)](-) layers via distorted [NaO(8)] polyhedra.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute for Chemical Technologies and Analytics, Division of Structural Chemistry, Vienna University of Technology, Getreidemarkt 9/164-SC, A-1060 Vienna, Austria.

ABSTRACT
The hydro-thermally prepared title compound, sodium iron(III) bis-[trioxotellurate(IV)], is isotypic with its Ga(III) analogue and consists of corrugated layers with an overall composition of [FeTe(2)O(6)](-) together with Na(+) cations. The layers extend parallel to (001) and are made up of [Fe(2)O(10)] edge-shared octa-hedral dimers and TeO(3) trigonal pyramids sharing vertices. The Na(+) cations are located in the cavities of this arrangement and link adjacent [FeTe(2)O(6)](-) layers via distorted [NaO(8)] polyhedra.

No MeSH data available.


Related in: MedlinePlus

The [Fe2O10] dimer with the corner-sharing TeO3 trigonal-pyramids attached. Atoms are drawn as displacement ellipsoids at the 90% probability level. [Symmetry operators: (i) -x + 1, -y + 1, z; (ii) -x + 1/2, y + 1/2, -z + 1; (iii) x + 1/2, -y + 1/2, z - 1; (iv) x - 1/2, -y + 1, -z + 1/2; (v) -x + 1/2, -y + 1/2, z - 1; (vi) -x + 1, -y + 1/2, z - 1/2; (vii) x, y + 1/2, -z + 1/2; (viii) -x + 1.5, y, z - 1/2; (ix) x + 1/2, -y + 1, -z + 1/2.]
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Fap2: The [Fe2O10] dimer with the corner-sharing TeO3 trigonal-pyramids attached. Atoms are drawn as displacement ellipsoids at the 90% probability level. [Symmetry operators: (i) -x + 1, -y + 1, z; (ii) -x + 1/2, y + 1/2, -z + 1; (iii) x + 1/2, -y + 1/2, z - 1; (iv) x - 1/2, -y + 1, -z + 1/2; (v) -x + 1/2, -y + 1/2, z - 1; (vi) -x + 1, -y + 1/2, z - 1/2; (vii) x, y + 1/2, -z + 1/2; (viii) -x + 1.5, y, z - 1/2; (ix) x + 1/2, -y + 1, -z + 1/2.]


NaFe(TeO(3))(2).

Weil M, Stöger B - Acta Crystallogr Sect E Struct Rep Online (2007)

The [Fe2O10] dimer with the corner-sharing TeO3 trigonal-pyramids attached. Atoms are drawn as displacement ellipsoids at the 90% probability level. [Symmetry operators: (i) -x + 1, -y + 1, z; (ii) -x + 1/2, y + 1/2, -z + 1; (iii) x + 1/2, -y + 1/2, z - 1; (iv) x - 1/2, -y + 1, -z + 1/2; (v) -x + 1/2, -y + 1/2, z - 1; (vi) -x + 1, -y + 1/2, z - 1/2; (vii) x, y + 1/2, -z + 1/2; (viii) -x + 1.5, y, z - 1/2; (ix) x + 1/2, -y + 1, -z + 1/2.]
© Copyright Policy - open-access
Related In: Results  -  Collection

License
Show All Figures
getmorefigures.php?uid=PMC2914881&req=5

Fap2: The [Fe2O10] dimer with the corner-sharing TeO3 trigonal-pyramids attached. Atoms are drawn as displacement ellipsoids at the 90% probability level. [Symmetry operators: (i) -x + 1, -y + 1, z; (ii) -x + 1/2, y + 1/2, -z + 1; (iii) x + 1/2, -y + 1/2, z - 1; (iv) x - 1/2, -y + 1, -z + 1/2; (v) -x + 1/2, -y + 1/2, z - 1; (vi) -x + 1, -y + 1/2, z - 1/2; (vii) x, y + 1/2, -z + 1/2; (viii) -x + 1.5, y, z - 1/2; (ix) x + 1/2, -y + 1, -z + 1/2.]
Bottom Line: The hydro-thermally prepared title compound, sodium iron(III) bis-[trioxotellurate(IV)], is isotypic with its Ga(III) analogue and consists of corrugated layers with an overall composition of [FeTe(2)O(6)](-) together with Na(+) cations.The layers extend parallel to (001) and are made up of [Fe(2)O(10)] edge-shared octa-hedral dimers and TeO(3) trigonal pyramids sharing vertices.The Na(+) cations are located in the cavities of this arrangement and link adjacent [FeTe(2)O(6)](-) layers via distorted [NaO(8)] polyhedra.

View Article: PubMed Central - HTML - PubMed

Affiliation: Institute for Chemical Technologies and Analytics, Division of Structural Chemistry, Vienna University of Technology, Getreidemarkt 9/164-SC, A-1060 Vienna, Austria.

ABSTRACT
The hydro-thermally prepared title compound, sodium iron(III) bis-[trioxotellurate(IV)], is isotypic with its Ga(III) analogue and consists of corrugated layers with an overall composition of [FeTe(2)O(6)](-) together with Na(+) cations. The layers extend parallel to (001) and are made up of [Fe(2)O(10)] edge-shared octa-hedral dimers and TeO(3) trigonal pyramids sharing vertices. The Na(+) cations are located in the cavities of this arrangement and link adjacent [FeTe(2)O(6)](-) layers via distorted [NaO(8)] polyhedra.

No MeSH data available.


Related in: MedlinePlus